@InProceedings{OkamotoMascBuenViei:2015:DeCaMá,
author = "Okamoto, Sayuri and Maschio, Leandro Jos{\'e} and Bueno,
Jos{\'e} Maria Correa and Vieira, Ricardo",
affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Universidade Federal
de S{\~a}o Carlos (UFSCar)} and {Instituto Nacional de Pesquisas
Espaciais (INPE)}",
title = "Desenvolvimento de catalisadores m{\'a}ssicos para
decomposi{\c{c}}{\~a}o do {\'o}xido nitroso para
aplica{\c{c}}{\~o}es aeroespaciais",
year = "2015",
organization = "Congresso Brasileiro de Cat{\'a}lise, 18.",
keywords = "mixed oxides, bulk catalysts, N2O decomposition, thruster.",
abstract = "Foram preparados catalisadores m{\'a}ssicos, {\`a} base de
{\'o}xidos Co, Mn e Al, para decomposi{\c{c}}{\~a}o do
{\'o}xido nitroso (N2O) para fins aeroespaciais a partir do
m{\'e}todo da coprecipita{\c{c}}{\~a}o. Este m{\'e}todo
consiste na coprecipita{\c{c}}{\~a}o de solu{\c{c}}{\~o}es de
nitratos de Co, Mn e Al em solu{\c{c}}{\~a}o de K2CO3, a 25°C,
mantendo o pH em 10 pela adi{\c{c}}{\~a}o de uma
solu{\c{c}}{\~a}o de KOH. Foram preparadas diversas raz{\~o}es
molares: 4Co1Mn1Al, 1Co4Mn1Al, 1Co2Mn, 2Co1Mn, 1Mn2Al e 1Co2Al.
Estes {\'o}xidos foram extrusados, calcinados a 900°C e
caracterizados por Adsor{\c{c}}{\~a}o de Nitrog{\^e}nio,
Quimissor{\c{c}}{\~a}o de CO, Termogravimetria, Difratometria de
Raios-X e por Espectroscopia de Fotoel{\'e}trons Excitados por
Raios-X (XPS). Inicialmente foram efetuados testes
catal{\'{\i}}ticos em um reator de leito fixo para
avalia{\c{c}}{\~a}o da atividade dos catalisadores na
temperatura de igni{\c{c}}{\~a}o da rea{\c{c}}{\~a}o de
decomposi{\c{c}}{\~a}o do N2O. Em seguida foram executados
testes em um propulsor de 2 N, empregando o catalisador com melhor
desempenho nos testes catal{\'{\i}}ticos (4Co1Mn1Al), para
verificar o performance do material, comparando com os valores
te{\'o}ricos. Foi, ainda, realizado um teste comparativo de
desempenho com o catalisador 5% Rh2O3/Al2O3, tradicionalmente
usado na decomposi{\c{c}}{\~a}o do N2O. ABSTRACT: Cobalt,
manganese and aluminum oxide-based bulk catalysts were prepared by
the coprecipitation method for decomposition of nitrous oxide
(N2O) for aerospace applications. Nitrates solutions of cobalt,
manganese, and aluminum were coprecipitated in a K2CO3 solution at
25°C, with pH maintained at 10 by adding a KOH solution. Several
oxides (4Co1Mn1Al, 1Co4Mn1Al, 1Co2Mn, 2Co1Mn, 1Mn2Al, 1Co2Al) were
prepared, extruded and calcined at 900°C. These materials were
characterized by N2 Adsorption, CO Chemisorption,
Thermogravimetry, X-Ray Diffraction, and X-ray Excited
Photoelectron Spectroscopy (XPS). The catalytic tests were first
performed in a fixed bed reactor in order to evaluate the
catalytic activity around the N2O decomposition temperature.
Afterwards, tests on a 2 N thruster were carried out with the
catalyst that has shown the best performance in the fixed bed
reactor (4Co1Mn1Al) and the experimental results were compared to
theoretical values. In addition, the performance of the bulk
catalyst was compared to the conventional catalyst (5%
Rh2O3/Al2O3) for N2O decomposition.",
conference-location = "Porto Seguro, BA",
conference-year = "13-17 set.",
urlaccessdate = "27 abr. 2024"
}